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Archaeological discovery shows that "Nanjing Man" lived in more than 500 thousand years ago.Zun, a kind of wine vessel, was found to exist in Beiyinyangying culture of Nanjing in about 5000 years ago.Nanjing served as the capital of Eastern Wu, one of the three major states in the Three Kingdoms period (211–280); the Eastern Jin and each of the Southern Dynasties (Liu Song, Southern Qi, Liang and Chen), which successively ruled southern China from 317–589; the Southern Tang, one of the Ten Kingdoms (937–76); the Ming dynasty when, for the first time, all of China was ruled from the city (1368–1421); The city also served as the seat of the rebel Taiping Heavenly Kingdom (1851–64) and the Japanese puppet regime of Wang Jingwei (1940–45) during the Second Sino-Japanese War.It suffered appalling atrocities in both conflicts, including the Nanjing Massacre.It renamed Jiangning (江寧) in Northern Song dynasty and renamed Jiankang in Southern Song dynasty.Jiankang's textile industry burgeoned and thrived during the Song dynasty despite the constant threat of foreign invasions from the north by the Jurchen-led Jin dynasty. especially strong in the chemical sciences, and also strong in many other areas, for instance, it hosts the nation's best computer software laboratory and wireless communication laboratory in IT field, as well as the state key laboratory of pharmaceutical biotechnology.

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The first emperor of the Ming dynasty, Zhu Yuanzhang (the Hongwu Emperor), who overthrew the Yuan dynasty, renamed the city Yingtian, rebuilt it, and made it the dynastic capital in 1368.Nanjing has served as the capital city of Jiangsu province since the establishment of the People's Republic of China.It boasts many important heritage sites, including the Presidential Palace and Sun Yat-sen Mausoleum. Situated in the Yangtze River Delta region, Nanjing has a prominent place in Chinese history and culture, having served as the capital of various Chinese dynasties, kingdoms and republican governments dating from the 3rd century to 1949, and has thus long been a major center of culture, education, research, politics, economy, transport networks and tourism, being the home to one of the world's largest inland ports.